整合生物学期刊网

Plant Diversity ›› 1998, Vol. 20 ›› Issue (04): 1-3.

• 研究论文 •    

毛喉鞘蕊花的微量成分

金歧端;和碧荷   

  1. 中国科学院昆明植物研究所植物化学开放研究室,昆明650204
  • 出版日期:1998-08-25 发布日期:1998-08-25

Minor Constituents from Coleus forskohlii

JIN Qi- Duan,HE Bi - He   

  1. Laboratory of Phytlchemistry, Kunming Institute of Botany, The Chinese Academy of Sciences, Kunming 650204
  • Online:1998-08-25 Published:1998-08-25

摘要: 从唇形科毛喉鞘蕊花(Coleus forskohlii)全草的的氯仿提取物分离到2个新的微量成分,鞘蕊花戊素和已素。基于光谱分析,鞘蕊花戊素和已素的化学结构分别鉴定为lα,7β-二乙酸氧基-8,13-环氧-6β羟基勒丹-14烯-11-酮(1)和7β-乙酰氧基-8, 13环氧-6β,9α-二羟基勒丹-14烯-11-酮(2)。

关键词: 鞘蕊花戊素, 鞘蕊花已素, 毛喉鞘蕊花, 唇形科, 二维核磁共振谱

Abstract: Two new labdanoids, forskolin E and F, with forskolin A, B, C and D, have been isolated from the chloroform extract of the whole plants of Coleus forskohlii. The chemical structures of the two minor constituents have been established as lα, 7β- diacetoxy- 8,13 epoxy- 6β- hydroxylabd- 14- en- 11 - one(l) and 7β-acetoxy- 8,13 - epoxy- 6β,9a- dihydroxylabd - 14- en- 11 - one(2), respectively, on the basis of detailed spectroscopic analysis and all assignments were supported by 1H -1H COSY, HMBC and HMOC spectrum (see table 1).

Key words: Forskolin E and F