整合生物学期刊网

Plant Diversity ›› 2006, Vol. 28 ›› Issue (04): 433-437.

• 研究论文 • 上一篇    

白粉藤的木脂素和三萜成分

王跃虎; 张仲凯; 何红平; 高锁; 孔宁川; 丁铭; 郝小江   

  1. 中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室
  • 收稿日期:2006-02-27 出版日期:2006-08-25 发布日期:2006-08-25
  • 通讯作者: 郝小江

Lignans and Triterpenoids from Cissus repens (Vitaceae)

WANG Yue-Hu; ZHANG Zhong-Kai; HE Hong-Ping; GAO Suo; KONG Ning-Chuan; DING Ming; HAO Xiao-Jiang   

  1. State Key Laboratory of Phytochemistry and Plant Resources in West China , Kunming Institute of Botany , Chinese Academy of Sciences
  • Received:2006-02-27 Online:2006-08-25 Published:2006-08-25
  • Contact: HAO Xiao-Jiang

摘要: 从白粉藤( Cissus repens Lank) 地上部分分离得到5 个木脂素和8 个三萜, 其中一个木脂素是新化合物, 它的结构通过波谱分析和碱水解的方法鉴定为: ( + )-异落叶松树脂醇-9′- (2-对-香豆酰)- O-β- D-吡喃木糖苷( 1)。其余化合物分别是: ( + ) -异落叶松树脂醇-9′- O-β- D-吡喃木糖苷( 2), ( + )-Lyoniside (3 ), ( ─ )-开环异落叶松树脂醇-9- O-β- D-吡喃木糖苷(4), (7′R, 8′S )-4′-hydroxy-3′, 5-dimethoxy-7′, 8′-dihydrobenzofuran- 1-propanolneolignan-9′- O-β-D-xylopyranoside (5), 木栓酮( 6 ), 表木栓醇( 7 ), 蒲公英赛醇乙酸酯( 8), 熊果酸(9), 2α-羟基乌索酸( 10), 积雪草酸(11), Niga-ichigoside F1 (12), 羽扇豆醇(13)。这些化合物都是首次从该植物中分离得到。

关键词: 白粉藤, 葡萄科, 木脂素, 五环三萜FONT

Abstract: Five lignans and eight triterpenoids were isolated from the aerial parts of Cissus repens. Among them, a lignan, ( + )- isolariciresinol-9′- (2- p-coumaric ) - O-β- D-xylopyranoside (1), was new and its structure was established on the basis of spectroscopic methods and alkaline hydrolysis. Other compounds, ( + ) -isolariciresinol-9′- O-β- D-xylopyranoside (2), ( + ) -lyoniside (3), ( ─) -secoisolariciresinol-9- O-β- D-xylopyranoside (4 ), ( 7′R, 8′S )-4′-hydroxy-3′, 5-dimethoxy-7′, 8′-dihydrobenzofuran-1-propanolneolignan-9′- O-β- D-xylopyranoside (5 ), friedelin ( 6 ), epifriedelanol ( 7), taraxerol-3β- acetate (8), ursolic acid (9 ), 2α-hydroxyursolic acid ( 10), asiatic acid (11 ), niga-ichigoside F1 ( 12 ) and lupeol (13), were found in the plant for the first time.

Key words: Cissus repens

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