Chirality pairing recognition, a unique reaction forming spiral alkaloids from amino acids stereoselectively in one-pot

doi:10.1007/s13659-012-0003-6

Natural Products and Bioprospecting ›› 2012, Vol. 2 ›› Issue (2): 53-58.DOI: 10.1007/s13659-012-0003-6

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Chirality pairing recognition, a unique reaction forming spiral alkaloids from amino acids stereoselectively in one-pot

Bing BAI^a,c, Da-Shan LI^a, Sheng-Zhuo HUANG^a, Jie REN^a,b, Hua-Jie ZHU^a,b

a State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, China;
b Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, College of Life Science, Hebei University, Baoding, 071002, China;
c Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2012-01-10 Revised:2012-02-21 Online:2018-02-11 Published:2012-04-24
Supported by:
Hua-Jie Zhu thanks the financial supports from NSFC(30873141), 973 Program(2009CB522300), Hebei University and the State Key Laboratory of Phytochemistry and Plant Resources in West China.

Chirality pairing recognition, a unique reaction forming spiral alkaloids from amino acids stereoselectively in one-pot

Bing BAI^a,c, Da-Shan LI^a, Sheng-Zhuo HUANG^a, Jie REN^a,b, Hua-Jie ZHU^a,b

a State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, China;
b Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, College of Life Science, Hebei University, Baoding, 071002, China;
c Graduate University of Chinese Academy of Sciences, Beijing 100049, China

通讯作者: Hua-Jie ZHU,E-mail:zhuhuajie@hotmail.com
基金资助:
Hua-Jie Zhu thanks the financial supports from NSFC(30873141), 973 Program(2009CB522300), Hebei University and the State Key Laboratory of Phytochemistry and Plant Resources in West China.

Abstract

Abstract: A novel chirality pairing recognition was found between D- and L-amino acid derivatives. Novel spiral alkaloids formed in the recognition reaction. Possible mechanism was proposed for the stereoselective and chemoselective reactions.

Key words: chirality pairing recognition reaction, spiral alkaloid, amino acid derivatives

摘要： A novel chirality pairing recognition was found between D- and L-amino acid derivatives. Novel spiral alkaloids formed in the recognition reaction. Possible mechanism was proposed for the stereoselective and chemoselective reactions.

关键词: chirality pairing recognition reaction, spiral alkaloid, amino acid derivatives

Bing BAI, Da-Shan LI, Sheng-Zhuo HUANG, Jie REN, Hua-Jie ZHU. Chirality pairing recognition, a unique reaction forming spiral alkaloids from amino acids stereoselectively in one-pot[J]. Natural Products and Bioprospecting, 2012, 2(2): 53-58.

Chirality pairing recognition, a unique reaction forming spiral alkaloids from amino acids stereoselectively in one-pot

Chirality pairing recognition, a unique reaction forming spiral alkaloids from amino acids stereoselectively in one-pot

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