整合生物学期刊网

Plant Diversity ›› 2008, Vol. 30 ›› Issue (02): 239-242.

• 研究论文 • 上一篇    下一篇

旋花茄新鲜果实中的三个甾体皂苷

滕希峰1 , 2 , 张颖君1, 杨崇仁1   

  • 收稿日期:2007-08-27 出版日期:2008-04-25 发布日期:2008-04-25
  • 通讯作者: 张颖君, 杨崇仁

Three Steroidal Glycosides from the Fresh Fruits of Solanum spirale (Solanaceae)

TENG Xi-Feng1 , 2 , ZHANG Ying-Jun1, YANG Chong-Ren1   

  • Received:2007-08-27 Online:2008-04-25 Published:2008-04-25
  • Contact: ZHANG Ying-Jun, YANG Chong-Ren

摘要: 从茄科食用植物旋花茄( Solanum spirale) 的新鲜果实中分离得到3 个化合物, 其中一个为新成分, 经现代波谱学方法鉴定为26- O-β-D-葡萄吡喃糖基-(25 R)-呋甾-3β, 22ξ, 26-三醇-5-烯-3-O-α-L-鼠李吡喃糖基- (1-2)- [3- O-(3- O-乙酰基)-α-L-鼠李吡喃糖基-(1-4) ]-β-D-葡萄吡喃糖苷( 1) 。2 个已知化合物分别为26- O-β-D-葡萄吡喃糖基-(25 R)-呋甾-22ξ-甲氧基-3β, 26-二醇-5-烯-3- O-α-L-鼠李吡喃糖基- (1-2 )-β-D-葡萄吡喃糖苷(2) 和26- O-β-D-葡萄吡喃糖基- (25 R) -呋甾-3β, 22ξ, 26-三醇-5-烯-3-O-α-L-鼠李吡喃糖基-( 1-2 )-[α-L-鼠李吡喃糖基-( 1-4) ]-β-D-葡萄吡喃糖苷( protodioscin) (3) , 均为首次从该植物中分离得到。

关键词: 茄科, 旋花茄, 甾体皂苷

Abstract: One new steroidal glycoside, 26-O-β-D-glucopyranosyl - ( 25 R)-furost-3β, 22ξ, 26-triol-5- ene-3-α-L-rhamnopyranosyl-(1-2) -[3 - O - (3- O-acetyl ) -α-L-rhamnopyranosyl -( 1-4 ) ] -β-D-glucopyranoside ( 1 ) were isolated from the fresh fruits of the edible plant Solanum spirale Roxb., together with two known ones, 26- O-β-D-glucopyranosyl - (25 R)-furost-22ξ-methoxyl-3β, 26-diol-5- ene-3- O-α-L-rhamnopyranosyl - (1-2)-β-D-glucopyranoside (2) and 26- O-β-D-glucopyranosyl-(25 R)-furost-3β, 22ξ, 26-triol-5-ene-3-O-α-L-rhamnopyranosyl -( 1-2 )- [α-L-rhamnopyranosyl - ( 1-4 ) ]-β Dglucopyranoside (protodioscin) (3). Their structures were elucidated by spectroscopic methods, especially 2D NMR. The known compounds 2-3 were isolated from the title plant for the first time.

Key words: Solanaceae

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