Integrative Biology Journals

Plant Diversity ›› 1995, Vol. 17 ›› Issue (03): 1-3.

• Articles •    

REVISION OF THE STRUCTURE OF STELLARIN A

ZHAO Yu-Rui ZHOU Jun WANG Xian-Kai HUANG Xiao-Lin WU Huo-Ming   

  1. Department of Medicinal Chemistry of Natural Products, School of Pharmacy,
  • Online:1995-06-25 Published:1995-06-25

千针万线草环肽A的结构修正

赵玉瑞 周俊 王宪楷 黄晓琳 吴厚铭   

  1. 华西医科大学药学院天然药物化学室

Abstract: From the fresh roots of Stellaria yunnanensis Franch. a new cyclopeptide named stellarin A, was obtained and its structure was established to be cyclo(Gly-Pro-Phe-Tyr-Gly-Gly-Pro) by FAB-MS in a previous communication.Recently by a combination of 2D-NMR, FAB-MS and enzymatic degradation,its structure was re-examined and revised to cyclo(Gly-Pro-Phe-Pro-Gly-Tyr-Gly).

Key words: Stellaria yunnanensis

摘要: 从云南民间药物千针万线草(Stellaria yunnanensis)的根中分离到一新环肽stellarin A。前报主要利用快速原子轰击质谱确定其结构为clo(Gly-Pro-Phe-Tyr-Gly-Gly-Pro)。最近利用最新二维核磁结合快速原子轰击质谱及酶降解重新考察了其结构,修正为cyclo(Gly-Pro-Phe-Pro-Gly-Tyr-Gly).

关键词: 针万线草, 石竹科, 环肽, 千针万线草环肽A